Journal of the Serbian Chemical Society 2012 Volume 77, Issue 4, Pages: 523-533
doi:10.2298/JSC110717191V
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Calculation of the effective diffusion coefficient during the drying of clay samples

Vasić Miloš, Radojević Zagorka, Grbavčić Željko

The aim of this study was to calculate the effective diffusion coefficient based on experimentally recorded drying curves for two masonry clays obtained from different localities. The calculation method and two computer programs based on the mathematical calculation of the second Fick’s law and Cranck diffusion equation were developed. Masonry product shrinkage during drying was taken into consideration for the first time and the appropriate correction was entered into the calculation. The results presented in this paper show that the values of the effective diffusion coefficient determined by the designed computer programs (with and without the correction for shrinkage) have similar values to those available in the literature for the same coefficient for different clays. Based on the mathematically determined prognostic value of the effective diffusion coefficient, it was concluded that, whatever the initial mineralogical composition of the clay, there is 90% agreement of the calculated prognostic drying curves with the experimentally recorded ones. When a shrinkage correction of the masonry products is introduced into the calculation step, this agreement is even better.

Keywords: diffusion, drying, mathematical modeling, computer program