Acta periodica technologica 2010 Issue 41, Pages: 169-176
doi:10.2298/APT1041169P
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Reactivity of 17β-hydroxy-17α-substituted androstane derivatives

Penov-Gaši Katarina M., Gaković Andrea R., Ajduković Jovana J., Đurendić-Brenesel Maja Đ., Đurendić Evgenija A., Savić Marina P., Sakač Marija N.

The work concerns the reactivity of 17β-hydroxy-17α-substituted androstanes 1-9. Depending on the nature of the 17α-substituent, the presence of the neighboring 16-oximino group, and the reagent used, these compounds can undergo retroaddition (10-12) and fragmentation-cyclization (14-16) reactions.

Keywords: androstane derivatives, retroaddition, fragmentation, cyclization reaction

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